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negative entropy of mixing for vanadium

negative entropy of mixing for vanadium

Mixing creates structural disorder so the entropy of a mixed system is expected to be larger than an unmixed system The wellknown configurational entropy of mixing in the point approximation Smix cf k B clnc 1 c ln 1 c 1 is always positive c is concentration 0c1 Its contribution to the free energy F E TS therefore promotes solubility at higher temperatures and in equilibrium with a second phase of


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